Arylation of Indoles with Supported Palladium Nanoparticles

doi:10.1055/s-0030-1259467

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Synfacts 2011(3): 0336-0336
DOI: 10.1055/s-0030-1259467

Polymer-Supported Synthesis

Arylation of Indoles with Supported Palladium Nanoparticles

Contributor(s): Yasuhiro Uozumi, Noboru Kobayashi
L. Wang, W.-b. Yi, C. Cai*
Nanjing University of Science and Technology, P. R. of China

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Publikationsdatum:
16. Februar 2011 (online)

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Significance

Fluorous silica gel (FSG) supported palladium nanoparticles (Pd-1/FSG) were prepared via immobilization of perfluoro chain functionalized benzene 1 stabilized palladium nanoparticles (Pd-1) on FSG by fluorous-fluorous interactions. Pd-1/FSG catalyzed the arylation of indoles with aryl halides to give the corresponding 2-arylindoles in up to 92% yield (19 examples).